close
Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2023 Aug 12;13(1):13135.
doi: 10.1038/s41598-023-40351-x.

An open carbon-phenolic ablator for scientific exploration

Affiliations

An open carbon-phenolic ablator for scientific exploration

Erik Poloni et al. Sci Rep. .

Abstract

Space exploration missions rely on ablative heat shields for the thermal protection of spacecraft during atmospheric entry flights. While dedicated research is needed for future missions, the scientific community has limited access to ablative materials typically used in aerospace. In this paper, we report the development of the HEFDiG Ablation-Research Laboratory Experiment Material (HARLEM), a carbon-phenolic ablator designed to supply the need for ablative materials in laboratory experiments. HARLEM is manufactured using polyacrylonitrile-based carbon fiber preforms and a simplified processing route for phenolic impregnation. We characterized the thermal protection performance of HARLEM in arcjet experiments conducted in the plasma wind tunnel PWK1 of the Institute of Space Systems at the University of Stuttgart. We assessed the performance of the new material by measuring surface recession rate and temperature using photogrammetry and thermography setups during the experiments, respectively. Our results show that HARLEM's thermal protection performance is comparable to legacy carbon-phenolic ablators that have been validated in different arcjet facilities or in-flight, as demonstrated by calculations of the effective heat of ablation and scanning electron microscopy of as-produced samples. In-house manufacturing of carbon-phenolic ablators enables the addition of embedded diagnostics to ablators, allowing for the acquisition of data on internal pressure and more sophisticated pyrolysis analysis techniques.

PubMed Disclaimer

Conflict of interest statement

The authors declare no competing interests.

Figures

Figure 1
Figure 1
(a) Processing steps used to prepare near-net-shape samples of the HEFDiG Ablation-Research Laboratory Experiment Material (HARLEM). Adapted with permission from Poloni et al.. (b) Frontal view of a HARLEM sample with density of 0.27g/cm3. Optical microscopy image featuring the resin-containing phase within the carbon fibers (inset).
Figure 2
Figure 2
Electron microscopy images of the carbon–phenolic ablators (a) HARLEM, (b) ASTERM and (c) PICA. Adapted with permission from Agrawal et al. and Pinaud et al.. Scale bars: 50μm.
Figure 3
Figure 3
(a) Plasma wind tunnel facility PWK1. (b) Photograph and schematics of a HARLEM sample mounted on the sample holder. (c) Schematics of the instruments arrangement used for photogrammetry and thermography.
Figure 4
Figure 4
Performance of carbon–phenolic ablators tested at the plasma wind tunnel facility PWK1. (a) Recession evolution characterized using photogrammetry of standard HARLEM samples (blue), a HARLEM sample manufactured with the preform FiberForm (red) and ZURAM samples (gray). The recession data for ZURAM was taken from Grigat et al.. (b) Temperature color map of a HARLEM sample acquired with an IR camera 5 s after the test start. The stagnation point is taken as a circular area in its center with a radius of 5 mm. (c) Stagnation-point temperature over time of the samples in (a) measured via thermography. The thermography data for ZURAM was taken from Grigat et al.. The blue and gray shaded areas are guides to the eye and indicate trends for HARLEM and ZURAM, respectively.

References

    1. Natali M, Kenny JM, Torre L. Science and technology of polymeric ablative materials for thermal protection systems and propulsion devices: A review. Prog. Mater. Sci. 2016;84:192–275. doi: 10.1016/j.pmatsci.2016.08.003. - DOI
    1. Uyanna O, Najafi H. Thermal protection systems for space vehicles: A review on technology development, current challenges and future prospects. Acta Astronautica. 2020;176:341–356. doi: 10.1016/j.actaastro.2020.06.047. - DOI
    1. White T, et al. Thermal protection system materials for sample return missions. Planet. Sci. Astrobiol. Decadal Surv. 2021;2023–2032(53):1–8. doi: 10.3847/25c2cfeb.72d83582. - DOI
    1. Bessire BK, Lahankar SA, Minton TK. Pyrolysis of phenolic impregnated carbon ablator (PICA) ACS Appl. Mater. Interfaces. 2015;7:1383–1395. doi: 10.1021/am507816f. - DOI - PubMed
    1. Bessire BK, Minton TK. Decomposition of phenolic impregnated carbon ablator (PICA) as a function of temperature and heating rate. ACS Appl. Mater. Interfaces. 2017;9:21422–21437. doi: 10.1021/acsami.7b03919. - DOI - PubMed

LinkOut - more resources